مولفه‌های اسید-باز ون در والس کشش سطح مایعات

Lifshitz-van der Waals/Lewis Acid–Base (LW–AB) Components of Liquid Surface Tensions

مولفه‌های اسید-باز ون در والس کشش سطح مایعات

    \[  {{\gamma }_L={\gamma }^d_L+{\gamma }^P_L} \]

مرجع

γL (mN/m) دهنده الکترون

γ+L (mN/m) پذیرنده الکترون

γLWL (mN/m) مولفه ون در والس

(℃) دما

فرمول شیمیایی

سیال

[ 1 ]

22.975

22.975

26.85

20

H2O

آب

[ 6,7 ]

25.5

25.5

21.8

[ 1 ]

22.218

22.218

26.85

30

[ 3 ]

24.55

24.55

21

37

[ 1 ]

21.461

21.461

26.85

40

[ 3 ]

24.15

24.15

20.6

44

[ 3 ]

22.6

22.6

19.3

70

[ 3 ]

21

21

17.9

95

[ 1 ]

23.87

9.43

34

20

C3H8O3

گلیسرول

[ 6 ]

57.4

3.92

34

[ 1 ]

24.35

8.88

34

30

[ 1 ]

24.46

8.48

34

40

[ 1 ]

19.20

4.70

29

20

C2H6O2

اتیلن گلیکول

[ 6,7 ]

47

1.92

29

[ 1 ]

20.90

3.93

29

30

[ 3 ]

45.5

1.86

28.1

37

[ 1 ]

21.49

3.45

29

40

[ 3 ]

45

1.84

27.8

44

[ 3 ]

43.4

1.77

26.8

70

[ 3 ]

41.7

1.71

25.7

95

[ 1 ]

24.62

3.68

39

20

C3H7NO

فرم آمید

[ 6,7 ]

39.6

2.28

39

[ 1 ]

24.43

3.38

39

30

[ 1 ]

25.79

2.91

39

40

[ 1,4 ]

0

0

50.8

20

CH2I2

دی یدومتان

[ 1 ]

0

0

49.42

30

[ 3 ]

0

0

48.3

37

[ 1 ]

0

0

48.05

40

[ 3 ]

0

0

47.3

44

[ 3 ]

0

0

43.8

70

[ 3 ]

0

0

40.5

95

[ 1 ]

0

0

45.40

20

C3H5Br3

تری برموپروپان

[ 1 ]

0

0

44.13

30

[ 1 ]

0

0

42.87

40

[ 1 ]

0

0

44.40

20

C10H7Br

برمو نفتالن

[ 6 ]

0

0

43.5

[ 1 ]

0

0

43.42

30

[ 1 ]

0

0

42.44

40

[ 4 ]

0

0

26.6

20

C14H13

تترا دکان

[ 4 ]

0

0

27.07

20

C15H32

پنتا دکان

[ 4 ]

0

0

18.4

20

C6H14

هگزان

[ 6 ]

32

0.5

32

20

C2H6OS

دی متیل سولفوکسید

[ 6 ]

0

3.8

27.15

20

CHCl3

کلروفرم

مراجع:

[ 1 ] Zdziennicka, A., Krawczyk, J., Szymczyk, K., & Jańczuk, B. (2017), Components and parameters of liquids and some polymers surface tension at different temperature, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 529, 864–875

[ 2 ] Cantin, S., Bouteau, M., Benhabib, F., & Perrot, F. (2006), Surface free energy evaluation of well-ordered Langmuir-Blodgett surfaces: Comparison of different approaches, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 276(1–3), 107–115

[ 3 ] Zhao, Q., Liu, Y., & Abel, E. W. (2004), Effect of temperature on the surface free energy of amorphous carbon films, Journal of Colloid and Interface Science, 280(1), 174–183

[ 4 ]Hwang, G., Lee, C. H., Ahn, I. S., & Mhin, B. J. (2011), Determination of reliable Lewis acid-base surface tension components of a solid in LW-AB approach, Journal of Industrial and Engineering Chemistry, 17(1), 125–129

[ 5 ] Ismail, M. F., Khorshidi, B., & Sadrzadeh, M. (2020), New insights into the prediction of adaptive wetting of a solid surface under a liquid medium, Applied Surface Science, 532

[ 6 ] . Leó, V., Tusa, A., & Araujo, Y. C. (1999), Determination of the solid surface tensions I. The platinum case, Colloids and Surfaces A: Physicochemical and Engineering Aspects, (Vol. 155)

[ 7 ] . Köstler, S., Delgado, A. v., & Ribitsch, V. (2005), Surface thermodynamic properties of polyelectrolyte multilayers, Journal of Colloid and Interface Science, 286(1), 339–348

مولفه‌های اسید-باز ون در والس کشش سطح مایعات

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