LW–AB Components of Liquid Surface Tensions

JikanCompany October 18, 2021October 19, 2021 Technical Note No Comments

Lifshitz-van der Waals/Lewis Acid–Base (LW–AB) Components of Liquid Surface Tensions

${{\gamma }_L={\gamma }^d_L+{\gamma }^P_L}$

Liquid	Chemical Formula	Temperture	γ^LW_L (mN/m) Van der waals	γ⁺_L (mN/m) Acceptor	γ^–_L (mN/m) Donord	Reference
Water	H₂O	20	26.85	22.975	22.975	[ 1 ]
		20	21.8	25.5	25.5	[ 6,7 ]
		30	26.85	22.218	22.218	[ 1 ]
		37	21	24.55	24.55	[ 3 ]
		40	26.85	21.461	21.461	[ 1 ]
		44	20.6	24.15	24.15	[ 3 ]
		70	19.3	22.6	22.6	[ 3 ]
		95	17.9	21	21	[ 3 ]
Glycerol	C₃H₈O₃	20	34	9.43	23.87	[ 1 ]
		20	34	3.92	57.4	[ 6 ]
		30	34	8.88	24.35	[ 1 ]
		40	34	8.48	24.46	[ 1 ]
Ethylene glycol	C₂H₆O₂	20	29	4.70	19.20	[ 1 ]
		20	29	1.92	47	[ 6,7 ]
		30	29	3.93	20.90	[ 1 ]
		37	28.1	1.86	45.5	[ 3 ]
		40	29	3.45	21.49	[ 1 ]
		44	27.8	1.84	45	[ 3 ]
		70	26.8	1.77	43.4	[ 3 ]
		95	25.7	1.71	41.7	[ 3 ]
Formamide	C₃H₇NO	20	39	3.68	24.62	[ 1 ]
		20	39	2.28	39.6	[ 6,7 ]
		30	39	3.38	24.43	[ 1 ]
		40	39	2.91	25.79	[ 1 ]
Diiodomethane	CH₂I₂	20	50.8	0	0	[ 1,4 ]
		30	49.42	0	0	[ 1 ]
		37	48.3	0	0	[ 3 ]
		40	48.05	0	0	[ 1 ]
		44	47.3	0	0	[ 3 ]
		70	43.8	0	0	[ 3 ]
		95	40.5	0	0	[ 3 ]
Tribromopropane	C₃H₅Br₃	20	45.40	0	0	[ 1 ]
		30	44.13	0	0	[ 1 ]
		40	42.87	0	0	[ 1 ]
Bromonaphthalene	C₁₀H₇Br	20	44.40	0	0	[ 1 ]
		20	43.5	0	0	[ 6 ]
		30	43.42	0	0	[ 1 ]
		40	42.44	0	0	[ 1 ]
Tetradecane	C₁₄H₁₃	20	26.6	0	0	[ 4 ]
Pentadecane	C₁₅H₃₂	20	27.07	0	0	[ 4 ]
Hexane	C₆H₁₄	20	18.4	0	0	[ 4 ]
Dimethyl sulfoxide	C₂H₆OS	20	32	0.5	32	[ 6 ]
Chloroform	CHCl₃	20	27.15	3.8	0	[ 6 ]

References:

[ 1 ] Zdziennicka, A., Krawczyk, J., Szymczyk, K., & Jańczuk, B. (2017), Components and parameters of liquids and some polymers surface tension at different temperature, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 529, 864–875

[ 2 ] Cantin, S., Bouteau, M., Benhabib, F., & Perrot, F. (2006), Surface free energy evaluation of well-ordered Langmuir-Blodgett surfaces: Comparison of different approaches, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 276(1–3), 107–115

[ 3 ] Zhao, Q., Liu, Y., & Abel, E. W. (2004), Effect of temperature on the surface free energy of amorphous carbon films, Journal of Colloid and Interface Science, 280(1), 174–183

[ 4 ] Hwang, G., Lee, C. H., Ahn, I. S., & Mhin, B. J. (2011), Determination of reliable Lewis acid-base surface tension components of a solid in LW-AB approach, Journal of Industrial and Engineering Chemistry, 17(1), 125–129

[ 5 ] Ismail, M. F., Khorshidi, B., & Sadrzadeh, M. (2020), New insights into the prediction of adaptive wetting of a solid surface under a liquid medium, Applied Surface Science, 532

[ 6 ] Leó, V., Tusa, A., & Araujo, Y. C. (1999), Determination of the solid surface tensions I. The platinum case, Colloids and Surfaces A: Physicochemical and Engineering Aspects, (Vol. 155)

[ 7 ] Köstler, S., Delgado, A. v., & Ribitsch, V. (2005), Surface thermodynamic properties of polyelectrolyte multilayers, Journal of Colloid and Interface Science, 286(1), 339–348

LW–AB Components of Liquid Surface Tensions

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